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Energy from Coal

Coal is odd stuff. It varies so much that sometimes you're not sure that it actually IS coal.

In parts of Yorkshire you can find lumps of sea coal on the beach . At Lyme Regis, where it's in compressed layers, you often find lumps of it washed up by the sea or coming out of the cliffs, uusually described by boffins as "shale". Brown coal from Germany is almost like peat, but it creates a stink when you burn it - it's full of sulphur and other nasties. Anthracite is shiny and black and almost clean when you touch it. And ordinary coal varies a lot- sometimes it even contains fossils. This isn't surprising considering that coal is the crushed remains of prehistoric forests. I found a fossil leaf once on a bit of coal, and there are lots of examples in museums.

Coke is different; it's coal with the dirtier bits removed, made by heating coal in a furnace without letting it burn. This is how they make "smokeless" fuel.

Coal is mainly CARBON. Pencil leads are made of the same stuff, and you probably know that it's called graphite. It burns incredibly cleanly. I knew a guy years ago who had to machine pieces of graphite -he used to take waste lumps home to burn on his fire. It contains an amazing amount of energy and sits there in the grate burning with NO smoke at all, glowing almost white-hot, with a pale blue flame ... in many ways an ideal fuel, unless you have to pay for it.

He said the only fuel to compare with it was old shoes, which surprised me.

Now ... carbon looks like this: the black dots are carbon atoms:

hexagons of carbon atoms joined together in graphite

Coal is similar to this - here's a picture I found many years ago:

proposed coal structure

and here's a close-up of part of it:


proposed coal structure, close-up


You can see this coal contains not only carbon but O and N (oxygen & nitrogen). You often get sulphur, too. This is bad news, because if you burn the coal, the smoke is acidic - and this means ACID RAIN.

Ordinary coal often contains about 2% sulphur by weight. So if you burn 100 tons of coal, you're burning 2 tons of sulphur. Here's what happens:

Sulphur + oxygen -----> sulphur dioxide
2 tons .........2 tons ...........4 tons

Add water to the sulphur dioxide, and you've got a little over 6 tons of sulphuric acid going up the smoke stack.

You can stop the acid going up the chimney by absorbing it and then chucking away (or using, if you can find a use for it) the spent absorber. Unfortunately the best absorbers are made from limestone, which means more quarries - big ones. Every 4 tons of sulphur dioxide needs 6 tons of limestone.

In the process you make about 6 tons of Plaster of Paris for every 100 tons of coal. You can fix a few thousand broken legs, and make a lot of plasterboard, but what can you do with the rest?

Landfill?

If so, what about local streams and ponds? Will they get polluted?

So far we've only looked at acid rain, but there's another problem - the "greenhouse" effect.

When you burn 100 tons of coal you form about 360 tons of carbon dioxide, all of which goes up the chimney.

When it reaches the upper atmosphere it starts to act rather like the glass in a greenhouse. The sun's rays hit the ground and the air warms up. The heat is trapped by the carbon dioxide, which is the "glass" and our planet gets a lot hotter than it should. At least, that's what the environmentalists say, and there seems to be increasing evidence that they're right.....it's unproveable, of course, which is why there's so much argument about it.

Many countries have flatly refused to limit their carbon dioxide emissions, including the U.S.A.....

How much coal is burned in UK power stations?

According to government statistics, about 50 million metric tons a year.

That's 50,000,000 tonnes, or about a million tons a week.

You can work out the sulphur dioxide, sulphuric acid and carbon dioxide for yourself.

Humans breathe out carbon dioxide, too .... we could even do some sums to see if we give out more than the power stations - but that'll have to be done on another page.....

Nigel Deacon / Habitat 21

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